Mechanism of Decrease in Corrosion Resistance of Cr Plated Parts Due to Heat Treatment and Measures to Prevent Decrease
Yuichi KOBAYASHI, Jun-ichi NAGASAWA, Toshihiko SASAKI and Yukio HIROSE
Abstract:The mechanism of decrease in the corrosion resistance of Cr plated parts when they are subjected to a heat-ing process and measures to prevent the decrease are studied. When the post finishing is performed after the Cr plating process, cracks in the Cr layer are closed as a result of plastic flow on the topmost surface layer. When the residual stress in the Cr layer becomes compressive due to the post finishing, the cracks are com-pletely closed, resulting in a high corrosion resistance. The residual stress in the Cr layer changes from com-pressive to tensile following heat treatment. When the residual stress becomes tensile, the cracks in the Cr layer which were closed during the post finishing open once again, resulting in a decrease in the corrosion resistance. We speculated that the change of residual stress from compressive to tensile is caused by the shrinkage of the Cr layer due to heat treatment, and the difference in the coefficients of thermal expansion between the substrate (steel) and Cr layer, as well as the release of residual stress generated during process-ing. In order to prevent the decrease of corrosion resistance under heat treatment, it is effective to apply compressive stress, which exceeds the level of change in residual stress due to heat treatment, to the Cr layer during the post finishing, after the Cr plating process. Key Words:Cr plating layer, Post finishing, Corrosion resistance, residual stress, X-Ray stress measurement, Heat treatment